intermediate 9 min read
Earth sciences · Topic
Atmospheric Thermodynamics
differential equations · probability theory · measure theory
Atmospheric thermodynamics applies classical thermodynamics to a compressible, moist ideal gas subject to gravity. Key quantities — potential temperature, equivalent potential temperature, and CAPE — determine whether parcels rise or sink and whether convection will be deep or suppressed. These concepts underpin everything from local thunderstorm forecasting to global circulation models.

Potential Temperature and Adiabatic Processes

Potential temperature $\theta$ is the temperature a parcel would have if brought dry-adiabatically to a reference pressure $p_0 = 1000\ \text{hPa}$:

\[\theta = T\left(\frac{p_0}{p}\right)^{R/c_p}\]

where $R = 287\ \text{J kg}^{-1}\text{K}^{-1}$ and $c_p = 1004\ \text{J kg}^{-1}\text{K}^{-1}$. For dry adiabatic ascent $\theta$ is conserved; it increases monotonically with height in a stable atmosphere.

Lapse Rates and Stability

Lapse rate Symbol Value
Dry adiabatic $\Gamma_d$ $9.8\ \text{K km}^{-1}$
Moist adiabatic $\Gamma_s$ $4–7\ \text{K km}^{-1}$
Environmental $\Gamma_e$ varies

The atmosphere is conditionally unstable when $\Gamma_s < \Gamma_e < \Gamma_d$. Saturation occurs at the lifting condensation level (LCL), above which the parcel cools at the moist adiabatic rate.

CAPE and Convective Potential

Convective Available Potential Energy measures the work done on a rising parcel between the Level of Free Convection (LFC) and the Equilibrium Level (EL):

\[\text{CAPE} = \int_{\text{LFC}}^{\text{EL}} g\,\frac{T_{v,\text{parcel}} - T_{v,\text{env}}}{T_{v,\text{env}}}\,dz\]

Values above $2500\ \text{J kg}^{-1}$ indicate the potential for severe convection. The skew-T log-p diagram provides a graphical framework for reading these integrals directly from radiosonde profiles.